Indicator Assessment

Atmospheric greenhouse gas concentrations

Indicator Assessment
Prod-ID: IND-2-en
  Also known as: CSI 013 , CLIM 052
Published 01 Jun 2016 Last modified 11 May 2021
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  • Global average concentrations of various greenhouse gases in the atmosphere continue to increase.
  • The concentration of CO2, the most important greenhouse gas, increased to 397 parts per million (ppm) in 2014 – an increase of 119 ppm (43 %) compared to pre-industrial levels.
  • The total concentration of all greenhouse gases, including cooling aerosols, reached a value of 441 ppm in CO2 equivalents in 2014 – an increase of about 3 ppm compared to 2013, and 34 ppm compared to totals measured more than 10 years ago.
  • The current total concentration of all greenhouse gases implies that the long-term probability of exceeding the 1.5 °C temperature increase, compared to pre-industrial levels, is already more than 50%. The atmospheric greenhouse gas concentration level that would be consistent with limiting global mean temperature increase to less than 2 °C could be exceeded over the next decades, unless greenhouse gas emissions are significantly reduced.

Contribution of different greenhouse gases to the overall greenhouse gas concentration

Chart 2014
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Chart 1990
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Chart 1950
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Atmospheric concentration of carbon dioxide, methane and nitrous oxide

Carbon dioxide
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Nitrous Oxide
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Greenhouse gas concentration levels in the atmosphere have increased during the 20th century and the first part of the 21st century, mainly as a result of human activities related to the use of fossil fuels (e.g. for power generation), agricultural activities and land-use change (mainly deforestation) (IPCC, 2013, see also Carbon Budget at Global Carbon Project, The increase in all greenhouse gases has been particularly rapid since 1950. In 1970, carbon dioxide (CO2) concentrations reached a level some 50 ppm above pre-industrial level recorded more than 200 years ago. The second 50 ppm increase took only around 30 years.

Each greenhouse gas (Text box 1) affects the climate system differently. To evaluate greenhouse gas concentrations in the atmosphere in relation to temperature change, it is important to consider all gases, i.e. the long-living greenhouse gases included in the Kyoto Protocol, those in the Montreal Protocol (direct and indirect), as well as ozone, water vapour and aerosols (IPCC, 2013). 

Text box 1: Greenhouse gases and their inclusion in international legislation 
Greenhouse gases can intercept solar radiation and, therefore, affect the climate system. In order to control the emissions of such gases, many of them are included in different international agreements, including the UNEP Montreal Protocol on Substances that Deplete the Ozone Layer (1987) and the Kyoto Protocol to the UNFCCC, which aims to limit global warming (1997). 
- Greenhouse gases included in the Kyoto Protocol (KPG) are: carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), and three (groups of) fluorinated gases; hydrofluorocarbons (HFC), perfluorocarbons (PFC) and sulfur hexafluoride (SF6).
- Greenhouse gases in the Montreal Protocol (MPG) cover three other groups of fluorinated gases: chlorofluorocarbons (CFC), hydrochlorofluorocarbons (HCFC) and methyl chloroform (CH3CCl3).
- In addition, there are also other forcing agents and greenhouse gases that are not included in global treaties but are dealt with at a regional level (e.g. the UNECE Convention on Long Range Transboundary Air Pollution), here called non-protocol gases (NPG), including tropospheric ozone (O3), and aerosols such as black carbon, sulphate and water vapour. 

Total greenhouse gas concentration and its relevance

The total CO2 equivalent concentration of all greenhouse gases reached 441 ppm in 2014, an increase of 3.3 ppm compared with 2013, and 34 ppm compared with 2004 (Figure 1).

The CO2 equivalent concentrations can be assessed in the light of the 2015 Climate Agreement in Paris. The objective of this agreement is ‘to hold the increase in the global average temperature to well below 2 °C above pre-industrial levels and to pursue efforts to limit the temperature increase to 1.5 °C above pre-industrial levels’ (UNFCCC, 2015). The CO2 equivalent concentration can be defined so as to correspond to a specific equilibrium warming (i.e. the long-term temperature increase).

Table 1 shows that the current total atmospheric greenhouse gas concentration already exceeds that which would keep long-term warming below the ‘temperature threshold’ of +1.5 oC. A concentration level of 480 ppm CO2 equivalents is ‘likely’ (= 67 % probability) to limit long-term global temperature increase to less than 2 oC (Table 1). This level is only about 40 ppm higher than the current concentration level. Assuming that the 2004–2013 trend of annual increase in total greenhouse gas concentration (i.e. 3.3 ppm per year) will continue in the coming years, this 480 ppm ‘threshold’ will be exceeded within the next 11 years (Table 1). A 50 % likelihood (‘about as likely as not’) of keeping the increase in the global average temperature below 2 °C corresponds with a concentration of 530 ppm CO2 equivalents (IPCC, 2013). Under a continuation of current trends, this level will be reached in less than 30 years. 

Table 1: Long-term concentration levels of greenhouse gases in the atmosphere consistent with keeping the global average temperature increase below 1.5 °C and 2 °C, for various probability levels. The number of years within which these concentrations could be exceeded are provided in brackets, given the trend of the past 10 years (source, IPCC, 2013; Meinshausen et al., 2009):

Probability of staying below target



67 % (likely)

Not calculated

480 ppm (11 years)

50 % (about as likely as not)

430 ppm (exceeded in 2012)

530 ppm (27 years)

10 % (unlikely)

530 ppm (27 years)

650 ppm (63 years)

Long-term data sets on tropospheric ozone concentrations are difficult to develop, due to the scarcity of representative observation sites with long-term records and the large spatial heterogeneity (IPCC, 2013).

Furthermore, note that for the total equivalent greenhouse gas concentration values presented, new estimates on the climate forcing of aerosols have been used (IPCC, 2013). Overall, aerosols have a cooling effect, although certain aerosols (e.g. black carbon) have a warming effect. The cooling effect is now estimated to be 0.4 watts per square metre (W/m2) smaller (i.e.  more warming) than previously thought, mainly due to the greater warming potential of black carbon (see also the section on uncertainty).

Relevance of individual gases

An assessment of the contribution by the various groups of greenhouse gases has shown that the NPGs compensate for nearly 20 % of the current forcing induced by the KPGs and MPGs. The MPGs, as a group, contribute about 9 % to current forcing (Figure 2). Concentrations of these gases peaked around 2000 and have been declining ever since, due to natural removal processes (IPCC, 2013). Most of the forcing is caused by KPGs, especially CO2.

The average annual CO2 concentration reached 397 ppm in 2014 (Figure 3). This is an increase of more than 119 ppm (43%), compared to pre-industrial levels (i.e. before 1800) (NOAA, 2015). Overall, CO2 concentrations in the atmosphere exceed the range of concentrations as recorded in ice cores over the past 800 000 years (IPCC, 2013).

The average annual concentration of methane (CH4) – the second most important greenhouse gas – reached 1 822 parts per billion (ppb) in 2014, increasing by a factor of 2.4 compared to pre-industrial levels (Figure 3). CH4 concentrations in the atmosphere were relatively stable between 2000 and 2006, but have been steadily increasing again since 2007. The exact drivers of this increase are still debated (IPCC, 2013).

The nitrous oxide (N2O) concentration was 327 ppb in 2014, 20 % above the pre-industrial level (Figure 3).

The group of fluorinated gases (F-gases) within the scope of the Kyoto Protocol can be categorised as HFCs, PFCs and SF6. The HFC group, in particular, is very broad. Concentrations of these F-gases have increased substantially over recent decades. Their contribution to current climate forcing is currently still limited, although steadily increasing (from 0.5 % in 1990 to 0.8 % in 2004, and 1.3 % in 2014, see Figure 2). Their contribution is expected to continuously increase in the near future, due to the long lifetimes of most F-gases (in some cases more than 1 000 years) and to the increase in the emissions of new HFCs such as HFC-134a (a substitute for CFCs, used because they do not have an ozone depleting impact in the stratosphere).

Supporting information

Indicator definition

This indicator shows the observed trends in greenhouse gas concentrations. Greenhouse gases differ in the way they affect the climate system. In order to sum the effects of the individual greenhouse gasses and other forcing agents in the atmosphere, the so-called ‘greenhouse gas equivalent concentration’ has been defined. This is the concentration of CO2 that would cause the same amount of radiative forcing as a mixture of CO2 and other forcing agents (greenhouse gases and aerosols). The forcing is expressed here in CO2-equivalent concentrations, rather than watts per square meter (W/m2), because they are more easily understood by the general public. For a more detailed assessment of radiative forcing expressed in W/m2, the reader is referred to IPCC (2013).

Global average annual concentrations are presented here. Although greenhouse gases are mainly emitted in the northern hemisphere, the use of global average values is considered justified, because the atmospheric lifetime of most greenhouse gases is long compared to the timescales of global atmospheric mixing. This leads to a rather uniform mixture around the globe. The exceptions are ozone and aerosols. However, as described earlier, these gases are less relevant, over the long term.


Atmospheric concentration is measured in parts per million CO2-equivalents (ppm CO2 eq.).


Policy context and targets

Context description

The overall objective of the United Nations Framework Convention on Climate Change (UNFCCC), is ‘to stabilise atmospheric greenhouse gas concentrations at a level that would prevent dangerous anthropogenic interference with the climate system’ (UNFCCC, 1993). Both at global level (UNFCCC, 2009) and EU levels (October 2008 Environment Council conclusions), this ‘dangerous anthropogenic interference’ has been recognised in an ambition to keep the long-term global average temperature rise below 2 °C, compared to pre-industrial levels. In December 2015, the Paris Agreement strengthened this by stating its objective as ‘holding the increase in the global average temperature to well below 2 °C above pre-industrial levels and to pursue efforts to limit the temperature increase to 1.5 °C above pre-industrial levels’(UNFCC, 2015).

CO2 equivalent concentration levels can be defined that correspond to these and other temperature increases. Note that these temperature increases represent a specific long-term equilibrium warming. The equilibrium climate sensitivity is defined as the change in global mean temperature, T2x, that results when the climate system, or a climate model, attains a new equilibrium with the forcing change, F2x, resulting from a doubling of the atmospheric CO2 concentration (IPCC, 2013).

Studies have been done to assess the probability of achieving this objective. These include both the 1.5 °C and 2 °C targets (above pre-industrial levels) in relation to various stabilisation levels of greenhouse gases in the atmosphere (Meinshausen et al., 2009, 2011; Van Vuuren et al., 2011; IPCC, 2014), which would result in the main objective of the COP21 Paris agreement being achieved (see also Table 1).

From estimates on climate sensitivity, it can be derived that the concentration of all greenhouse gases in the atmosphere – including ozone, water vapour and aerosols – would need to remain below approximately 430 ppm CO2 equivalent to achieve a 50 % probability of keeping the increase in global mean temperature below 1.5 °C. This concentration that is lower than the one currently observed. The atmospheric concentration level of all greenhouse gases that would be consistent with a maximum temperature increase of 2 °C is between 480 ppm and 650 ppm CO2 equivalent. Respectively, these figures give a 67 % and <10 % probability of staying below these temperature thresholds, see Table 1). 


In 1992, countries adopted the United Nations Framework Convention on Climate Change (UNFCCC) to cooperatively consider options for limiting average global temperature increases and the resulting climate change.[1] Continuous discussions under the UNFCCC led to the adoption, in 1997, of the Kyoto Protocol [2], which legally binds developed countries to achieve greenhouse gas emissions reduction targets.

In 2010, the international community agreed on the need to reduce emissions in order to prevent global temperature increases from exceeding 2 °C compared to pre-industrial levels[3] (no more than 1 °C above today's level). Scenarios consistent with this target show global emissions reductions of 40 % to 70% by 2050, compared to 2010 levels (i.e. 40 % to 60 % for scenarios with negative emissions, and 60 % to 70% for scenarios without negative emissions).[4]

More than 90 countries agreed to take on mitigation commitments until 2020, including the major developed and developing nations. The European Union (EU) and a small additional number of developed countries made their commitments under the Doha Amendment to the Kyoto Protocol for a second commitment period running from 2013 to 2020.[5] To secure the chance to stay below 2 °C, the international community has decided to work towards an international climate agreement for the period after 2020, which should be applicable to all. Such a new global agreement was concluded at the COP21 meeting in Paris, in November 2015. The sum of the proposed emissions reductions for all countries would still be insufficient to meet the target (UN Gap analysis).

[1] United Nations Framework Convention on Climate Change, United Nations (9 May 1992) New York, accessed 3 July 2014.

[2] Kyoto Protocol, United Nations Framework Convention on Climate Change, accessed 3 July 2014.

[3] Decision 1/CP.16: The Cancun Agreements: Outcome of the work of the Ad Hoc Working Group on Long-term Cooperative Action under the Convention, accessed 3 July 2014.

[4] IPCC (2014): Summary for Policymakers, In: Climate Change 2014, Mitigation of Climate Change. Contribution of Working Group III to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Edenhofer, O., R. Pichs-Madruga, Y. Sokona, E. Farahani, S. Kadner, K. Seyboth, A. Adler, I. Baum, S. Brunner, P. Eickemeier, B. Kriemann, J. Savolainen, S. Schlömer, C. von Stechow, T. Zwickel and J.C. Minx (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, accessed 3 July 2014.

[5] Doha Amendment to the Kyoto Protocol, Doha (8 December 2012), accessed 27 August 2014. 

Related policy documents

  • Council Decision (2002/358/EC) of 25 April 2002
    Council Decision (2002/358/EC) of 25 April 2002 concerning the approval, on behalf of the European Community, of the Kyoto Protocol to the United Nations Framework Convention on Climate Change and the joint fulfilment of commitments thereunder.
  • Greenhouse gas monitoring mechanism Decision
    Decision No 280/2004/EC of the European Parliament and of the Council of 11 February 2004 concerning a mechanism for monitoring Community greenhouse gas emissions and for implementing the Kyoto Protocol
  • Paris Agreement
    The Paris Agreement. Report of the Conference of the Parties on its twenty-first session, held in Paris from 30 November to 11 December 2015.


Methodology for indicator calculation

The trends in global average concentrations of atmospheric CO2 are taken directly from NOAA (NOAA, 2015, see also Global average concentration values for the other gases are mainly based on AGAGE figures (2014) (see These global figures were derived by averaging the data from four observatory stations across the world, equally distributed over the northern and southern hemispheres.

Radiative forcings are calculated using an approximate equation according to IPCC (2013), based on the observed atmospheric concentrations and using radiative efficiencies for CO2, CH4, N2O, ozone (both stratospheric and tropospheric) and vapour. IPCC (2013) estimates were also used for the radiative forcing of aerosols between 1970 and 2013.

The equations used to compute the contribution of individual gases are presented below: 

Trace gas

Parameterisation, radiative forcing, change in forcing (F) (Wm-2)

Constants (IPCC, 2013, Butler, 2009)


change in F = alpha ln (C/C0)

C and C0 are the current and pre-industrial concentrations (ppm) of CO2, respectively

alpha = 5.35


change in F = alpha (sq. root of M - sq. root of M0 ) - (f (M,N0) - f (M0,N0))


f (M,N)= 0.47 ln [1+2.01*10-5 (MN)0.75 + 5.31*10-15 M(MN)1.52]

M and M0 are the current and pre-industrial concentrations (ppb) of CH4, respectively; N and N0 are the current and pre-industrial concentrations (ppb) of N2O, respectively.

alpha  = 0.036


change in F = alpha (sq. root of N - sq. root of N0 ) - (f (M0,N) - f (M0,N0))




f (M,N)= 0.47 ln [1+2.01*10-5 (MN)0.75 + 5.31*10-15 M(MN)1.52]

M and M0 are the current and pre-industrial concentrations of CH4, respectively; N and N0 are the current and pre-industrial concentrations of N2O, respectively.

alpha  = 0.12


change in F = alpha (X-X0)

 X and X0 are the current and pre-industrial concentrations (ppb) of gas X, respectively.

Values for alpha depend on molecule (see below), taken from WMO, 2002.

 A similar approach was applied for the Montreal Protocol gases (i.e. CFCs and HCFCs):

CFCs and HCFCs

change in F = alpha (X-X0)

 X and X0 are the current and pre-industrial concentrations (ppb) of gas X, respectively.

Values for alpha depending on molecule (see below), taken from WMO, 2002.

Overview of used alpha values for chlorine Kyoto and Montreal Gases (also see CDIAC):

Kyoto gases

Alpha values

Montreal gases

Alpha values





















































In calculating the radiative forcing (and accompanying concentration levels) of the Montreal Protocol gases, the effect of ozone depleting substances on the stratospheric ozone layer was also considered. A factor of -0.154 for correcting the forcing of Montreal Protocol gases, based on IPCC (2013) (= -0.05 W/m2 or 10 ppm in 2014), was used. 

To quantify the total concentration of all greenhouse gases, the forcing of tropospheric ozone, water vapour in the atmosphere, cloud interaction, changes in albedo (e.g. due to black carbon) and the direct effects of multiple aerosols were added. Due to uncertainties in the measurements, and the large inter-annual and seasonal variation, forcing for tropospheric ozone, water vapour and land-use change was kept constant over the years at a respective 0.4, 0.07 (IPCC, 2013, p. 696) and 0.15 W/m2 (IPCC, 2013, p. 698).

For aerosols, we used figures (i) based on recent the IPCC report. For example, the forcing of black carbon (BC) from fossil fuel and biofuel use has increased as a result of increased emissions, especially in east and southeast Asia; (ii) changed the methodology for the period from 1970 to 2014. In this new methodology radiative forcing figures for for sulphate, black carbon, organic carbon, nitrate and other forcers (= sum of mineral dust, cloud interaction and contrails), based on IPCC (2013, Fig. 8.17, pg. 698), were defined. These figures are provided in the table below. Then the radiative forcing for these five groups back to 1970 was calculated. For sulphate, historical emissions data from Klimont et al. (2013) and IPCC (2013, Figure 8.8, p. 683) were used. For black carbon, organic carbon and nitrate, we used the historical radiative forcing figures as given by the IPCC (Figure 8.8, p. 683). Note that here the forcing of biomass burning was kept to zero, as it is balanced by a positive forcing due to black carbon and negative forcing from organic carbon (see also IPCC, 2013, Table 8.4).

Calculated radiative forcing for multiple aerosols for some years in the past (all in W/m2) is presented below.

Gas (group)















OC (incl. sec.)










Other gases










Methodology for gap filling

If measurement data from a particular station are missing for a certain year, the global trend is derived from data available from other stations. 

Methodology references

  • CDIAC for CFC-113 HCFC-22, HCFC-141b, HCFC-142b HFC-125, HFC-134a, HFC-152a, HFC-365mfc, HFC-23 Halon-1211, Halon-1301 CH3Cl, CH2Cl2, CHCl3, CH3Br CH3CCl3, CHClCCl2, CCl2CCl2 SF6, SO2F2 PFC-14, PFC-116, PFC-218 HFC-227ea HFC-236fa HFC-245fa
  • CDIAC for CH 4 , N 2 O, CO, H 2 , CFC-11, CFC-12, CH3CCl3, CCl4, CFC-113, and CHCl3. 
  • IPCC (2007) Climate Change 2007: The Physical Science Basis.  (eds.) Solomon S, Qin D, Manning M, Chen Z, Marquis M, Averyt K, Tignor MMB & Miller HL,. Working Group 1 Contribution to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC). Technical Summary and Chapter 10 (Global Climate Projections)
  • WMO (2002) Scientific Assessment of Ozone Depletion: 2002, Global Ozone Research and Monitoring Project–Report No. 47, World Meteorological Organization), Geneva, Switzerland
  • IPCC (2013) Climate Change 2013: The Physical Science Basis. Working Group 1 Contribution to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC). Technical Summary and Chapter 2.


Methodology uncertainty

Global average concentrations since approximately 1980 are determined by averaging measurements from several ground-station networks (SIO, NOAA/CMDL,ALE/GAGE/AGAGE), each network consisting of several stations distributed across the globe.

Absolute accuracies of global annual average concentrations are of the order of 1 % for CO2, CH4 and N2O, and CFCs; for HFCs, PFCs, and SF6, absolute accuracies can be up to 10 % -20 %. However, the year-to-year variations are much more accurate (IPCC, 2013).

Radiative forcing is calculated using parameterisations that relate the measured concentrations of greenhouse gases to radiative forcing. The overall uncertainty in radiative forcing calculations is shown in the tables below (given in 10 % and 90 % confidence ranges).

Best estimate values and 10 % and 90 % confidence ranges for total forcing (IPCC, 2013) are presented below:



Best estimate

10 %

90 %






















Montreal F-gases





Tropospheric O3





Sulfate aerosols





Nitrate aerosols





Black carbon





Organic carbon





Cloud Interaction





 Land use










Mineral dust





Air contrails









Another way of showing the effect of uncertainties on the total greenhouse gas concentration is to use alternative values for the forcing of aerosols. New estimates of this forcing have been presented in previous years (IPCC, 2013). The cooling effect of aerosols is now estimated to be 0.35 W/m2 smaller (= more warming) than reported in previous years, mainly due to the greater warming potential of black carbon. When using these older values, the total greenhouse gas concentration in 2014 is estimated to be about 34 ppm lower than when using the more recent figures. Given a similar trend in time, this lower concentration level would imply an additional 10 years before the various critical concentration levels (Table 1) would be reached. 

Overall, this shows the effect of a lower climate sensitivity (Rogelj et al., 2014) and higher heat uptake by the oceans (Doney et al., 2014). An important question here is whether this increased heat uptake will prove to be structural, over time. 

Data sets uncertainty

Comparability of direct measurements is good. Although methods for calculating radiative forcing and CO2 equivalent are expected to be further improved, any update of these methods will be applied to the complete data set covering all years, so this will not affect the comparability of the indicator over time. 

Rationale uncertainty

Atmospheric concentrations of greenhouse gases are a well-established indicator of changes in atmospheric composition, which causes changes in the global climate system. 

Data sources

Other info

DPSIR: State
Typology: Descriptive indicator (Type A - What is happening to the environment and to humans?)
Indicator codes
  • CSI 013
  • CLIM 052
Frequency of updates
Updates are scheduled once per year
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