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Emissions of ozone precursors (CSI 002) - Assessment published Dec 2012
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Emissions of the main ground-level ozone precursor pollutants have decreased across the EEA-32 region between 1990 and 2010; nitrogen oxides (NO X ) by 42%, non-methane volatile organic compounds (NMVOC) by 53%, carbon monoxide (CO) by 61%, and methane (CH 4 ) by 32%.
This decrease has been achieved mainly as a result of the introduction of catalytic converters for vehicles, which has significantly reduced emissions of NO X and CO from the road transport sector, the main source of ozone precursor emissions.
The EU-27 as a whole has not met its 2010 target to reduce emissions of NO X , one of the two ozone precursors (NO X and NMVOC) for which emission limits exist under the EU's NEC Directive (NECD). Whilst total NMVOC emissions in the EU-27 were below the NECD limit in 2010, a number of individual Member States did not meet their ceilings for one or both of these two pollutants.
Of the three non-EU countries having emission ceilings for 2010 set under the UNECE/CLRTAP Gothenburg protocol (Liechtenstein, Norway and Switzerland), all reported NMVOC emissions in 2010 that were lower than their respective ceilings, however Liechtenstein and Norway reported NO X emissions higher than their ceiling for 2010.
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Emissions of ozone precursors
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Change in ammonia emissions for each sector between 1990 and 2009 (EEA member countries)
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Percentage change in ammonia (NH3) emissions for each sector between 1990 and 2009.
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Distance-to-target for EEA member countries
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The distance-to-target indicator shows how current NH3 emissions compare to a linear emission reduction 'target-path' between 2010 emission levels and 2020 Gothenburg emission ceilings for each country. Negative percentage values indicate the current emissions in a country are below the linear target path; positive values show that current emission lie above a linear target path to 2020.
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Change in ammonia emissions for each sector between 1990 and 2010 (EEA member countries)
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Percentage change in ammonia (NH3) emissions for each sector between 1990 and 2010.
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Emission trends of selected heavy metals (EEA member countries - indexed 1990 = 100)
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Emission trends 1990-2009 for cadmium (Cd), mercury (Hg) and lead (Pb).
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Change (%) in cadmium emissions 1990-2009 (EEA member countries)
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The reported change in cadmium (Cd) emissions for each country, 1990-2009.
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Heavy metal (HM) emissions (APE 005) - Assessment published Dec 2011
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Across the EEA-32 countries, emissions of lead have decreased by 91%, mercury by 68% and cadmium by 70% between 1990 and 2009. For each substance, the most significant sources in 2009 are from energy-related sources associated with fuel combustion, particularly from public power and heat generating facilities, and from industrial facilities.
Much progress has been made since the early 1990s in reducing point source emissions of cadmium and lead (e.g. emissions from industrial facilities). This has been achieved through improvements in for example abatement technologies for wastewater treatment, incinerators and in metal refining and smelting industries, and in some countries by the closure of older industrial facilities as a consequence of economic re-structuring.
In the case of mercury, the observed decrease in emissions may be largely attributed to improved controls on mercury cells used in industrial processes (e.g. in the chlor-alkali process) including the replacement of old mercury cells by diaphragm or membrane cells, and the general decline of coal use across Europe as a result of fuel switching.
The promotion of unleaded petrol within the EU and in other EEA member countries through a combination of fiscal and regulatory measures has been a particular success story. EU Member States have for example completely phased out the use of leaded petrol, a goal that was regulated by Directive 98/70/EC. From being the largest source of lead in 1990 when it contributed around 73% of total emissions, emissions from the road transport sector decreased since then by nearly 99%. Nevertheless, the road transport sector still remains an important source of lead, contributing around 10% of total lead emission in the EEA-32 region. However since 2002 little progress has been made in reducing emissions further; 98% of the total reduction from 1990 emissions of lead had been achieved by 2002.
Environmental context: Heavy metals (such as cadmium, lead and mercury) are recognised as being toxic to biota. All have the quality of being progressively accumulated higher up the food chain, such that chronic exposure of lower organisms to much lower concentrations can expose predatory organisms, including humans, to potentially harmful concentrations. In humans they are also of direct concern because of their toxicity, their potential to cause cancer and their potential ability to cause harmful effects at low concentrations. The relative toxic/carcinogenic potencies of heavy metals are compound specific. Specifically, exposure to heavy metals has been linked with developmental retardation, various cancers and kidney damage. Metals are persistent throughout the environment, and cadmium, lead and mercury are among those heavy metals that are already a focus of international and EU action. These substances tend not just to be confined to a given geographical region, and thus are not always open to effective local control. For example, in the case of cadmium, much is found in fine particles which do not readily dry deposit, rather having long residence times in the atmosphere and hence are subject to long-range transport processes.
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Heavy metal (HM) emissions
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Non-methane volatile organic compounds (NMVOC) emissions (APE 004) - Assessment published Dec 2012
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EEA-32 emissions of non-methane volatile organic compounds (NMVOCs) have decreased by 53% since 1990. In 2010, the most significant sources of NMVOC emissions were 'Solvent and product use' (42%), comprising activities such as paint application, dry-cleaning and other use of solvents, followed by 'Commercial, institutional and households' (18%).
The decline in emissions since 1990 has primarily been due to reductions achieved in the road transport sector due to the introduction of vehicle catalytic converters and carbon canisters on petrol cars for evaporative emission control, driven by tighter vehicle emission standards, combined with limits on the maximum volatility of petrol that can be sold in EU Member States, as specified in fuel quality directives. The reductions in NMVOC emissions have been enhanced by the switching from petrol to diesel cars in some EU countries, and changes in the 'Solvents and product use' sector as a result of the introduction of legislative measures limiting the use and emissions of solvents.
The majority of EU-27 Member States have reduced emissions since 1990 in line with their obligations under the National Emission Ceilings Directive (NECD), however two Member States have not met their ceilings (Germany and Spain) [1] . Emissions in 2010 for the three non-EU countries which have emission ceilings for 2010 set under the UNECE/CLRTAP Gothenburg protocol (Liechtenstein, Norway and Switzerland) were all well below their respective ceilings.
Environmental context: Non-methane volatile organic compounds (NMVOCs) are a collection of organic compounds that differ widely in their chemical composition but display similar behaviour in the atmosphere. NMVOCs are emitted into the atmosphere from a large number of sources including combustion activities, solvent use and production processes. Biogenic NMVOC are emitted by vegetation, with amounts dependent on the species and on temperature. NMVOCs contribute to the formation of ground-level (tropospheric) ozone, and certain species such as benzene and 1,3 butadiene are directly hazardous to human health. Quantifying the emissions of total NMVOC provides an indicator of the emissions of the most hazardous NMVOCs.
[1] Emissions data reported by EU member states under NECD is used for comparison with NECD ceilings, and data reported under CLRTAP is used for all other calculations unless otherwise stated.
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Non-methane volatile organic compounds (NMVOC) emissions
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Heavy metal (HM) emissions (APE 005) - Assessment published Dec 2012
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Across the EEA-32 countries, emissions of lead have decreased by 89%, mercury by 63% and cadmium by 60% between 1990 and 2010. For each substance, the most significant sources in 2010 are from energy-related fuel combustion, particularly from public power and heat generating facilities, and from industrial facilities.
Much progress has been made since the early 1990s in reducing point source emissions of cadmium and lead (e.g. emissions from industrial facilities). This has been achieved through improvements in, for example, abatement technologies for wastewater treatment, incinerators and in metal refining and smelting industries, and in some countries by the closure of older industrial facilities as a consequence of economic re-structuring.
In the case of mercury, the observed decrease in emissions may be largely attributed to improved controls on mercury cells used in industrial processes (e.g. in the chlor-alkali process) including the replacement of old mercury cells by diaphragm or membrane cells, and the general decline of coal use across Europe as a result of fuel switching.
The promotion of unleaded petrol within the EU and in other EEA member countries through a combination of fiscal and regulatory measures has been a particular success story. EU Member States have completely phased out the use of leaded petrol, a goal that was regulated by Directive 98/70/EC. From being the largest source of lead emissions in 1990, when it contributed around 75% of the EEA-32 total for lead, emissions from the road transport sector have decreased by nearly 99%. Nevertheless, the road transport sector still remains an important source of lead, contributing around 10% of total lead emissions in the EEA-32 region. However since 2002 little progress has been made in reducing emissions further; 98% of the total reduction from 1990 emissions of lead had been achieved by 2002.
Environmental context: Heavy metals (such as cadmium, lead and mercury) are recognised as being toxic to biota. All are prone to biomagnification, i.e. being progressively accumulated higher up the food chain, such that bioaccumulation in lower organisms at relatively low concentrations can expose higher consumer organisms, including humans, to potentially harmful concentrations. In humans they are also of direct concern because of their toxicity, their potential to cause cancer and their potential ability to cause harmful effects at low concentrations.
The relative toxic/carcinogenic potencies of heavy metals are compound specific, but exposure to heavy metals has been linked with developmental retardation, various cancers and kidney damage. Metals are persistent throughout the environment, and cadmium, lead and mercury are among those heavy metals that are already a focus of international and EU action. These substances tend not just to be confined to a given geographical region, and thus are not always open to effective local control. For example, in the case of cadmium, much is found in fine particles which do not readily dry-deposit, and therefore have long residence times in the atmosphere and are subject to long-range transport processes.
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Heavy metal (HM) emissions
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Change (%) in HCB emissions 1990-2010 (EEA member countries)
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The reported change in hexachlorobenzene (HCB) emissions for each country, 1990-2010.
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